화학공학소재연구정보센터
Advanced Functional Materials, Vol.25, No.11, 1648-1655, 2015
Dual Support System Ensuring Porous Co-Al Hydroxide Nanosheets with Ultrahigh Rate Performance and High Energy Density for Supercapacitors
Layered double hydroxides (LDHs) are promising supercapacitor electrode materials due to their high specific capacitances. However, their electrochemical performances such as rate performance and energy density at a high current density, are rather poor. Accordingly, a facile strategy is demonstrated for the synthesis of the integrated porous Co-Al hydroxide nanosheets (named as GSP-LDH) with dual support system using dodecyl sulfate anions and graphene sheets as structural and conductive supports, respectively. Owing to fast ion/electron transport, porous and integrated structure, the GSP-LDH electrode exhibits remarkably improved electrochemical characteristics such as high specific capacitance (1043 F g(-1) at 1 A g(-1)) and ultra-high rate performance capability (912 F g(-1) at 20 A g(-1)). Moreover, the assembled sandwiched graphene/porous carbon (SGC)//GSP-LDH asymmetric supercapacitor delivers a high energy density up to 20.4 Wh kg(-1) at a very high power density of 9.3 kW kg(-1), higher than those of previously reported asymmetric supercapacitors. The strategy provides a facile and effective method to achieve high rate performance LDH based electrode materials for supercapacitors.