The crystal and molecular structure of the cis-bis [4-chloro- N-(pyrrolidine-1-carbothioyl)-benzamido] copper(H) complex was determined by single-crystal X-ray diffraction. The title compound, C24H24N4O2 S2Cl2Cu, crystalizes in the triclinic space group P-1, with Z= 4 and unit cell parameters a= 8.3877(5) angstrom, b= 12.7904(8) angstrom, c= 24.160(2) angstrom, alpha = 95.923(l) degrees, beta = 96.001(l) degrees, and gamma = 95.048(l) degrees. The copper atom is 4-fold coordinated by 2 S and 2 0 atoms and shows a slightly distorted planar quadratic ligand arrangement.