Molecular Crystals and Liquid Crystals, Vol.611, No.1, 58-64, 2015
Change of the Prenematic Order in the Isotropic Phase Close to the Isotropic-Nematic Phase Transition with Increasing Aerosil Nanoparticles Density
The influence of the hydrophilic and hydrophobic aerosil nanoparticles density on the formation of the prenematic order close to the isotropic - nematic (I-N) phase transition is presented. The lowering of the activation energy, with the increase of aerosil nanoparticles density, suggests a change of the prenematic order in the isotropic phase. The temperature dependence of the static dielectric permittivity for 4-n-pentyl-4 '-cyanobiphenyl (5CB) exhibits an anomaly near the I-N phase transition. With the increase of aerosil density, a substantial modification in the anomaly of the static permittivity was observed in the isotropic phase. Indicated changes are different for hydrophilic and hydrophobic aerosil as a result of different surface interaction between nematic molecules and aerosil nanoparticles.
Keywords:prenematic order;liquid crystals;aerosil nanoparticles;activation energy;static electric permittivity anomaly;dielectric spectroscopy