Organic light-emitting diodes (OLEDs) based on conjugated polymers exhibiting polarized emission have attracted much attention because of their potential as backlights for conventional liquid crystal (LC) displays and 3-D displays. We have reported a new series of LC polymers based on donor-acceptor architecture containing an oxadiazole (OXD) and several amine moieties in the same side chain, which exhibit bipolar character with a wide energy band gap. In this study, to develop phosphorescent OLEDs with polarized emission, we synthesized a platinum complex, Pt(4-decyloxy) salen, with emitting property, and fabricated the device consisting of Pt complex as a guest and LC polymers as a host material. The Pt complex exhibited high thermal stability, good solubility and an emission peak at 530 nm in dichloromethane. To obtain electroluminescense from the Pt complex, we fabricated ITO/rubbed PEDOT:PSS/Pt(4-decyloxy) salen: host polymer/MgAg devices. The devices emitted a yellowish green light, which was dominated by the triplet emission of the platinum complex. In addition, polarized electroluminescence was observed in an aligned LC polymer film.