화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals, Vol.546, 72-78, 2011
Excluded Volume Effect on the Nematic Phase of Hard Spherocylinder Fluid in Contact with a Hard Wall
The nematic phase of hard spherocylinder fluid in contact with a hard wall is calculated using a density functional theory. A new trial distribution function with explicit consideration of the excluded volume effect between the spherocylinders and the wall is proposed. The new trial function gives a lower surface tension than without the excluded volume effect, but it results in a less-plausible tilted nematic director with respect to the wall.