화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals, Vol.512, 1955-1969, 2009
Experimental Study of Anchoring Characteristics and Splay-Bend Surface-Like Elasticity of Nematics with Using Non-Twisted Nematic Cells
Question of second-order terms in bulk elastic free energy functional for nematics is discussed and investigated experimentally. Under assumption that these surface-like terms contribute only to surface free energy functional, they were firstly substituted by boundary conditions. Several flat-parallel cells (of thickness from 1.9 mu m to 31.2 mu m) filled with 5CB nematics of planar initial orientation (induced by substrates covered with rubbed SE130 polyimide) were investigated in static electric fields by measurement of their optical transmittance influenced by planar deformation states. The splay and bend elastic constants and anchoring characteristics were determined from these experimental data. The polar anchoring for this nematics-substrate system can not be qualified uniquely as strong or weak. Simulated optical transmittance characteristics computed with using these parameters imitate results of experiment with good accuracy within measurement errors. It is demonstrated that precise determining of nematics-substrate coupling and nematics material parameters is sufficient for quantitative description of nematics deformations. Afterwards the values of components of the free energy of nematics layer corresponding to the bulk elastic deformation, bulk interaction with electric field, nematics interaction with boundary and splay-bend surface contribution are computed from experimental data in two cases which can be interpreted as weak and strong anchoring. The following comparison of them leads to conclusions on the negligible magnitude order of the splay-bend elastic constant.