화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals, Vol.485, 903-914, 2008
New figure of merit for tailoring optimal structure of the second order NLO chromophore for guest-host polymers
Reliability to forecast SHG efficiency using two sets of non linear optical (NLO) chromophore figures of merit (FOM) was tested. One of them predicts that SHG efficiency d(33) of the poled guest-host polymer is proportional to ground state dipole similar to mu(g), another to similar to 1/mu(g). Correlation of maximal achieved second order NLO efficiency of the PMMA based systems containing eight dimethylaminobenzylidene-1, 3-indandione (DMABI) related chromophores with proposed FOM have been analyzed. The best correlations were obtained with second set of FOM, especially if high dipole moment (mu(g) > 7D) chromophores are included in analysis.