For the first time, we have shown the possibility to obtain structurally ordered systems using structured (fractal) water as a solvent by taking a water-soluble polymer, poly- 1-vinyl-1,2,4-triazole (PVT), as an example. When. distilled water was used as a solvent, the films always have amorphous structure. The investigations of electronic properties of ordered PVT films show that the electronic properties of structured ordered PVT are similar as for crystal samples.