Molecular Crystals and Liquid Crystals, Vol.441, 143-152, 2005
Dielectric properties of twisted nematic liquid crystal displays fabricated by doping Ag-Pd metal nanoparticles having a long term stability
TN-LCDs particularly doped with the metal nanoparticles of Ag-Pd composite, which are protected by chemical covering with nematic liquid crystal, 5CB (K-15, Merck) as a ligand, are shown to exhibit a long term stability in the electro-optical (EO) effect featured by a frequency modulation with short response times of ms or sub-ms order. This device is called FM-LCD. The unique electro-optical characteristics of the FM-LCD were clarified in terms of the Maxwell-Wagner effect of a heterogeneous dielectrics, where the analysis is done using an equivalent circuit model rather than the conventional potential theory; and we derived the formulae of the dielectric strength and the dielectric relaxation time. The former is used to explain the FM-LCD effect and also to evaluate the effective electrical conductivity of the metal nanoparticle that will be 4.4 x 10(4)S/m, which is about 1 x 10(-3) times smaller than that of metal Ag, and the latter is expressed to demonstrate that the relaxation time decreases with increasing the concentration of metal nanoparticle for the first time.
Keywords:equivalent circuit model;FM-LCD;liquid crystal;metal nanoparticles;Maxwell-Wagner effect;TN-LCD