A static light scattering study of monomeric (uncured) and Electron Beam (EB) cured Tripropyleneglycoldiacrylate (TPGDA) and E7 (a nematic Liquid Crystal) systems is reported. This study includes a detailed investigation of the structural properties in terms of temperature, composition and scattering angle. Knowledge of the phase diagrams helps us to achieve a better understanding of the scattering curves and rationalize data in terms of the LC configuration inside droplets. The depolarized component of the scattered intensity measured under cross polarizers exhibits patterns reminiscent of anisotropic objects. The results can be correlated to the electro-optical responses of the investigated systems relevant to applications in display technology and smart windows.