In this study, three different surface-sensitive techniques, grazing incidence X-ray diffraction (GIXD), attenuated total reflectance Fourier transform infrared (ATR-FTIR), and X-ray photoelectron spectroscopy (XPS), were employed to analyze the local structure and composition around the surface region of a lithium ion conducting solid electrolyte sheet It was revealed that the local structure and composition changed depending on depth from the top surface of the sheet. At the very surface, there was a layer with expanded lattice and high Li composition. And with increasing the depth from the surface, lattice shrank sharply, and then expanded again gradually. The change in the lattice seemed to be accompanied by Li and Al composition. It was supposed that the change in the Li composition and structure is induced by combination of chemical reaction, segregation, and defect distribution. (C) 2015 Elsevier B.V. All rights reserved.