A coralline vanadium pentoxide nanorod architecture on an indium-doped tin oxide substrate for energy-efficient electrochromism has been prepared by a simple annealing treatment from an overfilled amorphous three-dimensionally ordered macroporous vanadia film. The coralline vanadium pentoxide nanorod architecture exhibited multicolor electrochromic performance (yellow, blue-green, and olive), high transmittance modulations (25% and 27% at the typical wavelengths of 460 nm and 1000 nm, respectively), and fast switching speeds (4.8 s for coloration and 7.2 s for bleaching at 890 nm). In addition, the coralline vanadium pentoxide nanorod architecture exhibited desirable cycle stability. After 100 cycles, negligible transmittance modulation decreased in the visible spectrum, and a decrease of only approximately 5.6% was found in the near-infrared spectrum. Cyclic voltammetry measurements indicated that the majority of the current response of the redox reactions of the coralline V2O5 nanorod architecture was surface controlled, which resulted in desirable cycling stability and fast switching speeds. A indium-doped tin oxide substrate/vanadia/liquid electrolyte/poly(3,4-ethylenedioxythiophene)/indium-doped tin oxide substrate electrochromic device was assembled, and the device showed multicolor changes with acceptable transmittance modulation and good cycling stability. (C) 2015 Elsevier B.V. All rights reserved.