화학공학소재연구정보센터
Solar Energy, Vol.118, 126-133, 2015
Enhanced dye sensitized solar cell performance with high surface area thin ZnO film and PEDOT:PSS
ZnO coated meso-porous nanocrystalline TiO2 films were prepared and the corresponding photoelectrodes were used in the fabrication of Dye-Sensitized Solar Cells (DSSCs) to investigate its influence along with platinum (Pt), poly(3,4-ethylenedioxythiophene: poly (4-styrene sulfonate)) [PEDOT:PSS] counter electrodes on incident-photon-to-current conversion efficiency (IPCE) and power conversion performance (eta). DSSCs fabricated based on the ZnO coated photoeletrodes exhibit an IPCE of 71% with n-value of 7.51 +/- 0.06% [short-circuit current density (J(SC)) = 17.93 +/- 0.07 mA/cm(2), open-circuit voltage (V-OC) = 0.66 +/- 0.01 V, fill factor (FF) = 0.62 +/- 0.01] under Air Mass 1.5 sunlight, higher as compared to the reference DSSCs fabricated under similar conditions for ZnO free photoelectrodes, which exhibited a-value of 6.11 +/- 0.02% (J(SC) = 15.04 +/- 0.04 mA/cm(2), V-OC = 0.68 +/- 0.01 V, FF = 0.60 +/- 0.01) with platinum decorated counter electrodes. The higher power conversion efficiency of DSSCs fabricated based on TiO2/ZnO electrode could be probably more competitive electron collection process due to sharper ZnO nanosoar paths. (C) 2015 Elsevier Ltd. All rights reserved.