Particle shape plays an important role in determining the engineering behaviour of granular materials. In this regard, characterisation and quantification of particle shape are essential for understanding the behaviour of granular materials. X-ray micro-computed tomography (mu CT) enables observation of particle morphology at ever-greater resolutions. The challenge has thus become extracting quantified shape parameters from these rich three-dimensional (3D) images. In this paper, we implement X-ray mu CT to obtain 3D particle morphology and utilize image processing and analysis techniques to quantify it at different scales. A novel framework is proposed to measure 3D shape parameters of form, roundness, and compactness. New 3D roundness indexes were formulated from the local curvature on reconstructed triangular surface mesh. Subsequently, this method is utilized to study the change of particle shape by single particle crushing tests on Leighton Buzzard sand (LBS) particles. It is found that compactness value (i.e., sphericity) could be influenced by both form and roundness. Then, the distributions of shape parameters are characterised by Weibull statistics. It shows that single particle crushing tests generate more irregular fragments which have smaller shape parameters with larger variance for the measured shape parameters. (C) 2015 Elsevier B.V. All rights reserved.