Molecular Crystals and Liquid Crystals, Vol.376, 201-206, 2002
Physical properties and crystal structures of charge transfer complexes based on EDOEDT-TTF (EOET)
The electrocrystallization of EOET in the presence of (Bu4N)AuBr2 afforded two kinds of complexes. beta"-(EOET)(2)AuBr2 shows metallic behavior down to liquid helium temperature, while alpha'-(EOET)(2)AuBr2 is a Mott-Hubbard type semiconductor.