Syntheses and physical properties of complexes of fullerene with magnetic metal porphyrins

Aizawa N; Hara H; Ishii T; Yamashita M; Miyasaka H; Matsuzaka H; Kodama T; Kikuchi K; Ikemoto I

Molecular Crystals and Liquid Crystals, Vol.376, 13-18, 2002

DOI10.1080/10587250210735 Export Citation

Syntheses and physical properties of complexes of fullerene with magnetic metal porphyrins

Aizawa N, Hara H, Ishii T, Yamashita M, Miyasaka H, Matsuzaka H, Kodama T, Kikuchi K, Ikemoto I

Crystals containing C-60 and M(OEP) (M2+ = Pd, Cu, Ag; OEP2- = octaethylporphinato) were synthesized. From the X-ray analysis of the cocrystallites, it is revealed that the porphyrin molecules are still remaining their planar structures without deforming to the fit to the curved surface of fullerene.

Keywords:fullerene;metal porphyrin