Polymer complexes of rhodium (II,II and II,III) acetamidate dimers bridged by pyrazine (pyz), 4,4'-bipyridine (4,4'-bpy), and 1,4-diazabicyclo[2.2.2]octane (dabco) have been prepared and characterized. Doping of the Rh(II,II) polymers with NOBF4 increased the electrical conductivities when the bridging ligands were pyz and 4,4'-bpy. The magnetic interaction through the bridging ligands was found to be weak for the Rh(II,III) polymers.