Some physical and chemical properties of three ilmenite samples: IL-F (purchased from the mineral dealership of A and F Krantz), IL-Q (Qara-aghaj deposit, Iran) and IL-K (Kahnuj deposit, Iran) were studied. The substitution of different amounts of Mg, Mn and V in the crystal structure of ilmenite was identified by microprobe analysis. Different amounts of hemoilmenite exsolution were observed inside all three ilmenite samples using SEM, electron microprobe and X-ray diffraction analysis. Using these analytical techniques, titanite phase was found inside the IL-K ilmenite. The XPS analysis indicated that the contents of Fe3+ are 5.66, 5.33 and 3.72% for IL-F, IL-Q and IL-K, respectively which are in good agreement with the amounts of hemoilmenite exsolution. Mg and V contents in the ilmenite crystal structure have a good negative correlation with lattice constants (LC), unit cell volume, crystallinity index, specific gravity and IEP, while the Mn content correlates positively with these parameters. The IEP determined as 4.2, 5.4 and 6.25 for IL-F, IL-Q and IL-K, respectively, has a negative correlation with Fe3+ ions and ilmenite floatability. In comparison with magnetic susceptibility, the electrical resistivity of ilmenite has a higher correlation with surface properties (IEP and floatability), lattice constants, and unit cell volume. (C) 2014 Elsevier Ltd. All rights reserved.