Organic contaminants are a growing threat to the environment that widely demands their degradation by high efficient photocatalysts. Thus, the proposed research work primely focuses on the efficient degradation of methyl orange using designed WO3-ZnO photocatalysts under both UV and visible light irradiation. Two different sets of WO3 nanostructures namely, monoclinic WO3 (m-WO3) and hexagonal WO3 (h-WO3) synthesizes in presence of a different structure directing agents. A specific dispersion technique allows the intimate contact of as-synthesized WO3 and ultra-violet active commercial ZnO photocatalyst in different weight variations. ZnO nanocrystal in presence of an optimum 10 wt% m-WO3 shows a high degree of photocatalytic activity under both UV and visible light irradiation compared to counterpart h-WO3. Symmetrical monoclinic WO3 assists to trap hole in UV, but electron arresting mechanism predominates in visible irradiation. Coupling of monoclinic nanocuboid WO3 with ZnO proves to be a promising photocatalyst in both wavelengths. (C) 2015 Elsevier Ltd. All rights reserved.