A cocatalytic effect of nitro compounds is described for the B(C6F5)(3)center dot H2O catalyzed azidation of tertiary aliphatic alcohols, enabling catalyst turnover for the first time and With a broad range of substrates. Kinetic investigations into this surprising effect reveal that nitro compounds induce a switch from first order concentration dependence in Bronsted acid to second order concentration dependence in Bronsted acid and second order dependence in the nitro compounds. Kinetic, electronic, and spectroscopic evidence suggests that higher order hydrogen-bonded aggregates of nitro compounds and acids are the kinetically competent Bronsted acid catalysts. Specific weak H-bond accepting additives may offer a new general approach to accelerating Bronsted acid catalysis in solution.