Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

Yoshida S; Yano T; Misawa Y; Sugimura Y; Igawa K; Shimizu S; Tomooka K; Hosoya T

Journal of the American Chemical Society, Vol.137, No.44, 14071-14074, 2015

Yoshida S, Yano T, Misawa Y, Sugimura Y, Igawa K, Shimizu S, Tomooka K, Hosoya T

A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.