A systematic assessment of the electrochemical activity of two different parent coal types, pyrolysed at temperatures between 500 and 900 degrees C higher heating temperature (HHT), is presented in this work. Analysis shows that certain coal chars are catalytically activated in molten carbonate media at 600 degrees C, however activity does not appear to follow trends established for ashless carbon sources. It is seen here that it is not possible to predict activity based solely on electrical resistance, surface functionalization, or the BET surface area of pyrolysed coals. Instead, it is suggested that coal ash type, abundance and distribution plays a pivotal role in activating the coal char to allow fast electrochemical oxidation through a catalytically enhanced pathway. Activation from ash influence is discussed to result from wetting of the molten carbonate media with the carbon surface (change in polarity of electrode surface), through ash mediated oxide adsorption and transfer to carbon particles, or possibly through another catalytic pathway not yet able to be predicted from current results. (C) 2015 Elsevier B.V. All rights reserved.