Nitrogen-doped 3D graphene frameworks (N-3D GFs) were synthesized by a facile two-step method: Polystyrene (PS) encapsulated in graphene oxide (GO) composites (denoted as PS@GO) are first synthesized, followed by a post-thermal annealing in ammonia step to get N-doped 3D GFs. The resulting N-3D GFs inherit the advantages of graphene, which possesses high electrical conductivity and high specific surface area. Furthermore, the well-defined 3D interconnected structure can facilitate the access of the electrolyte to the electrode surface, thus shortening the diffusion length of both keeping the overall electrode highly conductive and active in lithium storage. Simultaneously, the in-situ formation of pyridinic N and pyrrolic N in 3D GFs provide high electronic conductivity and structure stability for lithium storage. The designed N-3D GFs electrode delivers a high specific capacity of 1094 mAhg(-1) after 100 cycles at 200 mAg(-1) and superior rate capability (691 mAhg-1 after 500 cycles at 1000 mAg(-1)) when used as anode for LIBs. We believe that such an inherently inexpensive, scalable, facile method can significantly increase the feasibility of building high performance energy storage system. (C) 2015 Elsevier B.V. All rights reserved.