Journal of Power Sources, Vol.297, 174-180, 2015
Screen printed cathode for non-aqueous lithium-oxygen batteries
An issue with conventional non-aqueous Li-O-2 battery cathodes that are formed by spraying/brushing/casting/coating carbon black slurries is a lack of sufficiently large pores, vulnerable to clogging by solid discharge products, and hence resulting in a low capacity. In this work, we report a novel cathode structure formed by screen-printing method. This deposition method allows the creation of evenly distributed large pores (similar to 10 mu m). As compared with the cathode formed by slurry-coating method, the cathode formed by the present method increases the battery's capacity by two times. The cyclability is also seen a significant improvement. The improved performance may be attributed to large pores that give more appropriate distributions of discharge products and hence facilitate the transportation of oxygen during cycling. (C) 2015 Elsevier B.V. All rights reserved.