Water molecular dynamics in a hardened Portland cement were characterized by proton Fourier transform nuclear magnetic resonance (NMR) at 400 MHz. Three different types of water molecule (physically bound, chemically bound and porous trapped) were observed. When the hardened cement sample was heated at 105 degrees C, the physically bound water diffused out of the sample as a function of the heating time while the chemically bound water remained in a stable form. A trace amount of the porously trapped water was also detected to remain in the cavities of the hardened cement even after heating for up to 20 h at th is temperature. The loss of the physically bound water proved to be a diffusion-controlled process as evidenced from the NMR data and from a gravimetric technique. A Fake doublet was observed in the NMR spectra. This is a result of the oscillation of the water molecules with hindered molecular motions due to their entrapment in the cement pores. Soaking the dried samples in water resulted in the diffusion of water back into the hardened cement as physically bound water. Nuclear spin-spin relaxation time, T-2-weighted imaging showed that the distribution of the physically bound water inside the cylindrical sample formed a doughnut shape after overnight soaking. The residual air in the cement pores may have slowed down the diffusion rate of the water molecules back into the dried cement.