화학공학소재연구정보센터
Journal of Membrane Science, Vol.475, 480-487, 2015
Highly permeable and mechanically robust silicon carbide hollow fiber membranes
Silicon carbide (SiC) membranes have shown large potential for applications in water treatment. Being able to make these membranes in a hollow fiber geometry allows for higher surface-to-volume ratios. In this study, we present a thermal treatment procedure that is tuned to produce porous silicon carbide hollow fiber membranes with sufficient mechanical strength. Thermal treatments up to 1500 degrees C in either nitrogen or argon resulted in relatively strong fibers, that were still contaminated with residual carbon from the polymer binder. After treatment at a higher temperature of 1790 degrees C, the mechanical strength had decreased as a result of carbon removal, but after treatments at even higher temperature of 2075 degrees C the SiC-particles sinter together, resulting in fibers with mechanical strengths of 30-40 MPa and exceptionally high water permeabilities of 50,000 L m(-2) h(-1) bar(-1). Combined with the unique chemical and thermal resistance of silicon carbide, these properties make the fibers suitable microfiltration membranes or as a membrane support for application under demanding conditions. (C) 2014 Elsevier B.V. All rights reserved.