Journal of Membrane Science, Vol.492, 271-280, 2015
'Up-scaling' potential for polyelectrolyte multilayer membranes
The layer-by-layer method is an attractive technique for preparing ultrathin nanostructured polyelectrolyte multilayer membranes (PEMMs) with tailored composition and tunable properties. This paper investigates the optimization of the membrane preparation to render it more feasible from a practical view point. PEMMs were prepared with minimal number of bilayers and rinsing steps for two polyion combinations: poly(diallyldimethylammonium chloride) with poly (vinylsullonic acid sodium salt) and the same cation with poly(sodium 4-styrenesulfonate). Three bilayers proved optimal for SRINIE applications. The commonly applied rinsing process turned out to be non essential, In addition, two minutes dipping time per deposition step already proved sufficient for defect free SRNE membrane preparation. Thus, the build-up protocol for PEMMs was overall reduced to a 6-step coating procedure taking 12 min without compromising the SRNE properties, in contrast to the previously reported 20-80 steps which required upto 7 h. Therefore, the 'up scaling' potential of this type of membrane is significantly increased and potential production costs reduced. (C) 2015 Elsevier B.V. All rights reserved,
Keywords:Polyelectrolyte;Multilayer;Membrane;Layer-by-layer technique;Solvent resistant nanofiltration