Novel polymers having hole transport ability were prepared by condensation polymerization of triphenylamine derivatives (TPAs) and aldehydes such as paraformaldehyde (FA) or benzaldehyde . The polymers synthesized had high glass transition temperature in the range of 172-239℃ and were soluble in common organic solvents. The polymers had hole mobility in the range of 10^-5 to 10^-6 cm²/Vs. The electroluminescent (EL) devices were fabricated using polymers prepared from N,N''-diphenyl-N,N''-bis(4-methylphenyl)-(1,1''-biphenyl)-4,4''-diamine (TPD) as a hole transport layer and aluminum trisquinolinol as an electron transporting and emitting layer. It had turn on voltagel of 4V and maximum luminace of 10^-4 cd/m², which correspond to the device using low molecular weight compound.