The article attempted to prepare special acrylic adhesives with preferable adhesion property and better thermal stability by introducing a fluorinated monomer. The FT-IR result showed that fluorinated monomers and acrylic monomers participated in copolymerization successfully. Furthermore, fluorinated groups performed good compatibility with acrylic resins, based on differential scanning calorimetry curve. According to the TG test under different heating rates, the activation energy of PSAs containing different content of fluorinated monomers was calculated to evaluate the effect of hexafluorobutyl acrylate on heat resistance of PSAs. Then, the findings of contact angle test revealed that the fluorinated PSAs also had rather lower surface energy than ordinary PSAs. Finally, the results of peel strength measurements indicated that the fluorinated PSAs demonstrated excellent adhesion property on various materials, especially low surface energy substrates.