Kesterite Cu2ZnSnS4 (CZTS) with different crystallinities were obtained by high temperature recrystallization of as-prepared kesterite CZTS nanocrystals under elevated temperature. The effect of temperature on the crystallinity, crystallite size and specific surface area, thus the photocatalytic H-2 evolution activity were discussed in detail. The maximum photocatalytic H-2 evolution rate was achieved under an intermediate annealing temperature (450 and 550 degrees C), which show moderate crystallinity and specific surface area. However, the surface specific activity of CZTS, namely the amount of H-2 evolution per surface area, show the highest value when the annealing temperature increased up to 750 degrees C. A rapid cooling process which induces the improvement of crystallinity without significant loss of specific surface area was used to further enhance the photocatalytic H-2 evolution activity of CZTS. Crown Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.