Inorganic Chemistry, Vol.54, No.20, 9687-9689, 2015
Factors Impacting Electron Transfer in Cyano-Bridged {Fe2Co2} Clusters
A cyano-bridged {(Fe2Co2II)-Co-III} complex exhibits reversible thermally and photoinduced intramolecular charge transfer. Its desolvated, MeOH-d(4), and other analogues were compared to disclose the impact factors on the electron-transfer behavior of these {(Fe2Co2II)-Co-III} clusters.