화학공학소재연구정보센터
Fluid Phase Equilibria, Vol.408, 273-283, 2016
PC-SAFT modeling of petroleum reservoir fluid phase behavior using new correlations for petroleum cuts and plus fractions
Parameters of the PC-SAFT Equation of State (EoS) for pure components are generally determined by matching the saturation pressure and liquid density experimental data. These experimental data are unavailable for petroleum cuts and plus fractions of the petroleum reservoir fluids. In this work, new correlations as functions of specific gravity and molecular weight were developed to estimate the PC-SAFT parameters of petroleum cuts with unknown composition. It was shown that the proposed correlations accurately estimate the PC-SAFT parameters of the pure components published in the literature. Then, the obtained correlations were used and the PVT experimental data for varicius real reservoir fluids was modeled using the PC-SAFT EoS and the results were compared to the modeled results using the Peng-Robinson EoS. The obtained results showed that the PC-SAFT EoS along with the proposed correlations presents acceptable results for phase behavior modeling of the reservoir petroleum fluids. (C) 2015 Elsevier B.V. All rights reserved.