화학공학소재연구정보센터
Fluid Phase Equilibria, Vol.392, 1-11, 2015
Measurement of activity coefficient at infinite dilution for some bio-oil components in water and mass transfer study of bubbles in the dilutor
Activity coefficients at infinite dilution (gamma(infinity)) values are of great importance when designing separation processes like distillation, liquid-liquid extraction and gas stripping. In this study the gamma(infinity) values were determined for four compounds in water that are present in bio-oil. Henry's law constants (H-12), Partial molar excess enthalpies at infinite dilution ((H) over bar (E,infinity)(i)) and air-water partition coefficients (K-aw) are also reported. The measurements were performed using inert gas stripping equipment (dilutor) in the 298-340 K temperature range. Mass transfer study was also performed to investigate the equilibrium between the solution and the gas leaving the cell. (C) 2015 Elsevier B.V. All rights reserved.