Activated porous carbons containing both micropores and meso-/macropores are prepared by cost-effective pyrolysis carbonization and the subsequent alkali activation of a easily available biomass, paulownia flower (PF). The as-prepared activated PF carbons (a-PFCs) show high specific surface areas, suitable pore size distributions, superhydrophilicity and partial graphitization phase, all of which are essential for achieving high electrochemical performances as supercapacitor electrodes. The symmetric supercapacitor based on a-PFC3, which is synthesized at the mass ratio of KOH to PF derived carbon (PFC) to be 3 during activation step, offers a specific capacitance of 297 F g (1) at current density of 1 Ag (1) within potential range of # 2-3# 1V using 1MH(2)SO(4) electrolyte. Owing to the high specific capacitance and wide potential window, the supercapacitor delivers high energy densities of 44.5 similar to 22.2Wh kg (1) under the power outputs of 247 similar to 3781W kg (1). The high specific capacitance, good rate capability, superior cycling reliability and excellent capacitance maintaining ability in tandem cell group make the a-PFC3 supercapacitor a competitive unit in assembling of amplified tandem battery pack. (C) 2015 Elsevier Ltd. All rights reserved.