In this study, TiO2-GN nanocomposite working electrodes were fabricated by adding graphene nanosheets (GNs) to TiO2 thin-film working electrodes. The influence of the thickness of the TiO2 thin-film working electrodes on the efficiency and charge transport characteristics of the corresponding dye-sensitized solar cells (DSSCs) was investigated. A GN solution was spin-coated onto the TiO2 thin films, which were then sintered at 100 degrees C in order to fabricate TiO2-GN working electrodes. The characteristics of various working electrodes were analyzed via scanning electron microscopy, atomic force microscopy, surface profilometry, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and Raman spectroscopy. Moreover, the DSSCs fabricated from these working electrodes were characterized via current density-voltage, incident photo-to-current conversion efficiency, electrochemical impedance spectroscopy, intensity-modulated photocurrent spectroscopy, and intensity-modulated photovoltage spectroscopy measurements. The results indicate that adding GNs to TiO2 thin films can enhance the electron transport rate and charge collection efficiency in TiO2-GN working electrodes, and thereby increase the power conversion efficiency of DSSCs. As such, DSSCs containing the TiO2-GN working electrodes exhibited an efficiency of 8.07%, which is 24.3% higher than that (6.49%) of the DSSCs containing conventional TiO2 working electrodes. (C) 2015 Elsevier Ltd. All rights reserved.