Spectroelectrochemistry: ESR of Paramagnetic Intermediates in the Electron Transfer Series [Cr(bpy)(3)](n) (n=3+, 2+, 1+, 0, 1-)

Kholin K; Valitov M; Burilov V; Tselischeva E; Strekalova S; Mustafina A; Budnikova Y; Kadirov M

Electrochimica Acta, Vol.182, 212-216, 2015

DOI10.1016/j.electacta.2015.09.073 Export Citation

Spectroelectrochemistry: ESR of Paramagnetic Intermediates in the Electron Transfer Series [Cr(bpy)(3)](n) (n=3+, 2+, 1+, 0, 1-)

Kholin K, Valitov M, Burilov V, Tselischeva E, Strekalova S, Mustafina A, Budnikova Y, Kadirov M

A new method of cyclic voltammetry with simultaneous ESR spectra multiple recording (CV-MRESR) has been proposed and implemented. Along with cyclic voltammetry (CV) and electron spin resonance (ESR), the combined method involving cyclic voltammetry and ESR (CV-ESR) has been used for the study of electron transfer in a series of complexes [Cr(bpy)(3)](n) (n = 3+, 2+, 1+, 0, 1-). (C) 2015 Elsevier Ltd. All rights reserved.

Keywords:Transition metal complexes;pyridine ligands;radical anion;cyclic voltammetry;electron spin resonance