Desalination, Vol.365, 220-226, 2015
Synthesis of polyaspartic acid derivative and evaluation of its corrosion and scale inhibition performance in seawater utilization
A polyaspartic acid derivative (PASP-SEA-ASP) was synthesized from polysuccinimide with 2-aminoethanesulfonic acid and aspartic acid. PASP-SEA-ASP achieved a better corrosion inhibition rate for A3 carbon steel in seawater compared with polyaspartic acid (49% cf. 45% at the dosage of 100 mg/L). The development of a composite inhibitor (a mixture of PASP-SEA-ASP, zinc sulfate, 2-hydroxyphosphonoacetic acid (HPAA) and hexadecylldimethyl (2-sulfite) ethyl ammonium on a mass ratio of 15:3:6:1, respectively) led to a significantly enhanced corrosion inhibition effect, achieving an inhibition rate of 97%. The mass ratio of the composite inhibitor could be adjusted to achieve the desired corrosion inhibition rate for seawater with varying characteristics. PASP-SEA-ASP also showed excellent scale inhibition properties for seawater, with a scale inhibition rate of 100% achieved with a dosage of 14 mg/L This study demonstrated the potential of PASP-SEA-ASP to inhibit both corrosion and scale formation in domestic and industrial utilization of seawater such as cooling systems and thermal desalination processes. (C) 2015 Elsevier B.V. All rights reserved.
Keywords:Seawater;Polyaspartic acid;Polyaspartic add derivative;Scale inhibition;Corrosion inhibition