This article describes a novel experimental method to visualize the mode shapes of pressure oscillation in a cylindrical cavity. Acoustic resonance in a cavity is a grand old problem that has been under investigation (using both analytical and numerical methods) for more than a century. In this article, a novel method based on high speed imaging of combustion chemiluminescence was presented to visualize the mode shapes of pressure oscillation in a cylindrical cavity. By generating high-temperature combustion gases and strong pressure waves simultaneously in a cylindrical cavity, the pressure oscillation can be inferred due to the chemiluminescence emissions of the combustion products. The mode shapes can then be visualized by reconstructing the images based on the amplitudes of the luminosity spectrum at the corresponding resonant frequencies. Up to 11 resonant mode shapes were clearly visualized, each matching very well with the analytical solutions.