화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.35, 185-194, March, 2016
DOI10.1016/j.jiec.2015.12.030  Export Citation
Biosorption of Pb(II) onto immobilized and native Mangifera indica waste biomass
Raziya Nadeem†, Qaisar Manzoor, Munawar Iqbal1, †, and Jan Nisar1
  • Department of Chemistry, University of Agriculture, Faisalabad 38040, Pakistan
  • 1National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan
E-mail:,
The removal of Pb(II) from simulated solution and wastewater using native and immobilized Mangifera indica biomass (MIB) were studied as a function of pH, initial concentration, biosorbent dose and contact time. The biosorption data was analyzed using pseudo-first and pseudo-second order kinetic models and Langmuir, Freundlich and Temkin isotherms. The immobilized biomass did not show promising efficiency for the adsorption of Pb(II) as compared to native biomass. The SEM and EDX analysis confirmed the Pb(II) adsorption onto MIB. FTIR and desorption studies were also performed. The Langmuir model and pseudo-second order kinetic fitted well to the adsorption experimental data.
Keywords:Heavy metal;Kinetics study;Isotherms;Textile wastewater;Adsorption
  1. Bilal N, Ali S, Iqbal M, Asian J. Chem., 26, 1882 (2014)
  2. Iqbal J, Cecil F, Ahmad K, Iqbal M, Mushtaq M, Naeem M, Bokhari T, Asian J. Chem., 25, 2099 (2013)
  3. Iqbal M, Bhatti IA, Pak. J. Agric. Sci., 51, 1141 (2014)
  4. Iqbal M, Bhatti IA, J. Hazard. Mater., 299, 351 (2015)
  5. Iqbal M, Bhatti IA, Zia-ur-Rehman M, Bhatti HN, Shahid M, Asian J. Chem., 26, 4291 (2014)
  6. Iqbal M, Nisar J, J. Environ. Chem. Eng., 3, 1912 (2015)
  7. Jamal MA, Muneer M, Iqbal M, Chem. Int., 1, 12 (2015)
  8. Qureshi K, Ahmad MZ, Bhatti IA, Iqbal M, Khan A, Chem. Int., 1, 53 (2015)
  9. Sayed M, Chem. Int., 1, 81 (2015)
  10. Montazer-Rahmati MM, Rabbani P, Abdolali A, Keshtkar AR, J. Hazard. Mater., 185, 401 (2011)
  11. Hasan HA, Abdullah SRS, Kofli NT, Kamarudin SK, J. Environ. Manage., 111, 34 (2012)
  12. Acheampong MA, Pakshirajan K, Annachhatre AP, Lens PNL, J. Ind. Eng. Chem., 19(3), 841 (2013)
  13. Yurtsever M, Sengil IA, J. Hazard. Mater., 163(1), 58 (2009)
  14. Shinde NR, Bankar AV, Kumar AR, Zinjarde SS, J. Environ. Manage., 102, 115 (2012)
  15. Lugo-Lugo V, Barrera-Dıaz C, Urena-Nunez F, Bilyeu B, Linares-Hernandez I, J. Environ. Manage., 112, 120 (2012)
  16. Nadeem R, Ansari TM, Khalid AM, J. Hazard. Mater., 156(1-3), 64 (2008)
  17. Manzoor Q, Nadeem R, Iqbal M, Saeed R, Ansari TM, Bioresour. Technol. (2013)
  18. Ahmad M, Usman ARA, Lee SS, Kim SC, Joo JH, Yang JE, Ok YS, J. Ind. Eng. Chem., 18(1), 198 (2012)
  19. Naushad M, Khosravi-fard Y, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.05.002. (2013)
  20. Martı´n-Lara MA, Bla´zquez G, Ronda A, Rodrı´guez IL, Calero M, J. Ind. Eng. Chem., 18(3), 1006 (2012)
  21. Sauco VG, Mango Production and World Market: Current Situation and Future Prospects, 2002, p. 107.
  22. Bayo J, Chem. Eng. J. (2012)
  23. Ho YS, Chiu WT, Hsu CS, Huang CT, Hydrometallurgy, 73, 55 (2004)
  24. Ullah I, Nadeeem R, Iqbal M, Manzoor Q, Ecol. Eng., http://dx.doi.org/10.1016/j.ecoleng.2013.07.028. (2013)
  25. Haddad ME, Regti A, Slimani R, Lazar S, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.05.038. (2013)
  26. Bhatti HN, Bajwa II, Hanif MA, Bukhari IH, Korean J. Chem. Eng., 27(1), 218 (2010)
  27. Chen CY, Yang CY, Chen AH, J. Environ. Manage., 92, 796 (2011)
  28. Han RP, Zhang JH, Zou WH, Xiao HJ, Shi H, Liu HM, J. Hazard. Mater., 133(1-3), 262 (2006)
  29. Zubair A, Bhatti HN, Hanif MA, Shafqat F, Water Air Soil Pollut., 191, 305 (2008)
  30. Amarasinghe BMWPK, Williams RA, Chem. Eng. J., 132(1-3), 299 (2007)
  31. El-Ashtoukhy ESZ, Amin NK, Abdelwahab O, Desalination, 223(1-3), 162 (2008)
  32. Pehlivan E, Altun T, Parlayici S, J. Hazard. Mater., 164(2-3), 982 (2009)
  33. Riaz M, Nadeem R, Hanif MA, Ansari TM, Khalil-ur-Rehman, J. Hazard. Mater., 161(1), 88 (2009)
  34. Kilic M, Keskin ME, Mazlum S, Mazlum N, Chem. Eng. Process., 47(1), 31 (2008)
  35. Kiran I, Akar T, Tunali S, Process Biochem., 40, 3550 (2005)
  36. Alam M, Nadeem R, Jilani MI, Int. J. Chem. Biochem. Sci., 1, 48 (2012)
  37. Nasir MH, Nadeem R, Akhtar K, Hanif MA, Khalid AM, J. Hazard. Mater., 147(3), 1006 (2007)
  38. Al-Asheh S, Banat F, Al-Omari R, Duvnjak Z, Chemosphere, 41, 659 (2000)
  39. Ahmad A, Rafatullah M, Sulaiman O, Ibrahim MH, Chii YY, Siddique BM, Desalination, 247(1-3), 636 (2009)
  40. Liu YH, Cao QL, Luo F, Chen J, J. Hazard. Mater., 163(2-3), 931 (2009)
  41. Manzoor Q, Nadeem R, Iqbal M, Saeed R, Ansari TM, Bioresour. Technol., 132, 446 (2013)
  42. Yao ZY, Qi JH, Wang LH, J. Hazard. Mater., 174(1-3), 137 (2010)
  43. Ajmal M, Rao RAK, Ahmad R, Ahmad J, J. Hazard. Mater., 79(1-2), 117 (2000)
  44. Nadeem R, Hanif MA, Shaheen F, Perveen S, Zafar MN, Iqbal T, J. Hazard. Mater., 150, 335 (2008)
  45. Iqbal M, Saeed A, Zafar SI, J. Hazard. Mater., 164(1), 161 (2009)
  46. Reddy DHK, Harinath Y, Seshaiah K, Reddy AVR, Chem. Eng. J., 162(2), 626 (2010)
  47. Nadeem R, Ansari TM, Akhtar K, Khalid AM, Chem. Eng. J., 152(1), 54 (2009)
  48. Kapoor A, Viraraghavan T, Bioresour. Technol., 63(2), 109 (1998)
  49. Yan GY, Viraraghavan T, Bioresour. Technol., 78(3), 243 (2001)
  50. Lalhruaitluanga H, Jayaram K, Prasad MNV, Kumar KK, J. Hazard. Mater., 175(1-3), 311 (2010)
  51. Temkin M, Pyzhev V, Acta Physicochim. URSS, 12, 217 (1940)
  52. Aytas S, Turkozu DA, Gok C, Desalination, 280(1-3), 354 (2011)
  53. Razmovski R, Sciban M, Ecol. Eng., 34, 179 (2008)
  54. Qiu H, Lv L, Pan B, Zhang Q, Zhang W, J. Zhejiang Univ. Sci. A, 10, 716 (2009)
  55. Javed MA, Bhatti HN, Hanif MA, Nadeem R, Sep. Sci. Technol., 42(16), 3641 (2007)
  56. Weber W, Morris J, Advances in Water Pollution Research, 1962, p. 231.
  57. Ofomaja AE, Bioresour. Technol., 101(15), 5868 (2010)
  58. Kannan N, Meenakshisundaram M, Water Air Soil Pollut., 138, 289 (2002)
  59. Selatnia A, Boukazoula A, Kechid N, Bakhti M, Chergui A, Kerchich Y, Biochem. Eng. J., 19, 127 (2004)
  60. Yadava K, Tyagi B, Singh V, J. Chem. Technol. Biotechnol., 51, 47 (1991)
  61. Noeline BF, Manohar DM, Anirudhan TS, Sep. Purif. Technol., 45(2), 131 (2005)
  62. Shroff KA, Vaidya VK, Chem. Eng. J., 171(3), 1234 (2011)
  63. Abas SNA, Ismail MHS, Kamal ML, Izhar S, World Appl. Sci. J., 28, 1518 (2013)
  64. Krishnan KA, Sreejalekshmi KG, Baiju RS, Bioresour. Technol., 102(22), 10239 (2011)