The surface hydrophobicity of membrane is a key factor in contactor applications where the penetration of liquid into membrane pores has negative effect on the contactor performance. Therefore, different methods have been proposed for surface modification. Blending hydrophobic polymers such as surface modifying macromolecules (SMM) has been investigated in our earlier researches. In this study, the effect of polyvinylidene fluoride (PVDF) blending on the surface and bulk morphology of polyetherimide (PEI) hollow fiber membrane and its performance in membrane gas absorption process was studied. It was found that the pore size increased from 112 nm to 210 nm from the neat PEI membrane to the PEI membrane spun from the solution blended with 0.25 wt% PVDF. At the same time, the contact angle increased from 78.3 and 84.3. Furthermore, the absorption flux of PVDF blended membrane enhanced by 13% compared to the neat PEI membrane. (C) 2015 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.