화학공학소재연구정보센터
Journal of Materials Science, Vol.29, No.20, 5321-5326, 1994
Microstructural Development and Mechanical-Properties of Pressureless-Sintered SiC with Plate-Like Grains Using Al2O3-Y2O3 Additives
Dense SiC ceramics with plate-like grains were obtained by pressureless sintering using beta-SiC powder with the addition of 6 wt% Al2O3 and 4 wt% Y2O3. The relationships between sintering conditions, microstructural development, and mechanical properties for the obtained ceramics were established. During sintering of the beta-SiC powder compact, the equiaxed grain structure gradually changed into the plate-like grain structure that is closely entangled and linked together through the grain growth associated with the beta --> alpha phase transformation. With increasing holding time, the fraction of beta --> alpha phase transformation, the grain size, and the aspect ratio of grains, increased. Fracture toughness increased from 4.5 MPa m(1/2) to 8.3 MPa m(1/2) with increasing size and aspect ratio of the grains. Crack deflection and crack bridging were considered to be the main operative mechanisms that led to improved fracture toughness.