화학공학소재연구정보센터
Applied Surface Science, Vol.359, 500-507, 2015
Synthesis of multiwall carbon nanotube wrapped Co(OH)(2) flakes: A high-performance supercapacitor
The problem of poor electron conductivity is always associated with pseudocapacitive electrode material that deters full utilization of the active material. To have a viable solution to this problem, we report fabrication of a composite material bringing highly conductive carbon nanotube (CNT) wrapped pseudocapacitive with Co(OH)(2) nanoflakes. An in situ growth route evolves the supercapacitor via our laboratory developed modified hydrothermal reaction condition (MHT). An electrochemical investigation substantiates that the composite material electrode is highly active, which delivers a maximum specific capacitance of 603 F g(-1) (at 1 mV s(-1) scan rate), outstanding long-term cyclic stability with 96% retention at a constant current density of 1.5 A g(-1) after 1000 cycles of operation. Thus it offers almost an effortless approach to fabricate high-power and high-energy density supercapacitors. By virtue of having high-capacity of pseudocapacitive hydroxides and desirable conductivity of carbon-based materials, the as-synthesized material could be a promising candidate for the development of supercapacitor electrode material. (C) 2015 Elsevier B.V. All rights reserved.