The accumulation and dissipation of electrical charge on glass surfaces is of considerable academic and industrial interest. The purpose of the present article, is to report on the differences in charging kinetics of several flat alumina-borosilicate (low alkali content) glass surfaces via a rolling sphere test (RST) [I] that have been physically and/or chemically modified by different approaches and exposed to variable environmental conditions (i.e. relative humidity). Methods used for surface modification include chemical etching (HF based chemistries of variable molarity) and plasma processing/thin film deposition (CH4 via Reactive Ion Etch (RIE) and/or Atmospheric Pressure Plasma Chemical Vapor Deposition (APPCVD)). Trends in glass surface charge rates, along with corresponding surface resistivity, energy and zeta potential measurements indicate that glass surface, and perhaps bulk, chemistry (specifically a surface' reactivity/affinity with/to water) play critical roles in charge dynamics. Based on the results, we propose an ion-based transfer model facilitated by surface-water molecular interactions as the primary mechanism responsible for contact electrification in glass-metal contact systems. (C) 2015 Elsevier B.V. All rights reserved.