Cobalt ferrites (CoFe2O4) nanoparticles were implanted into the ordered mesoporous cobaltosic oxide (Co3O4) nanowires to synthesize magnetic CoFe2O4/Co3O4 nanocomposites. X-ray diffraction (XRD), N-2 physical absorption-desorption, transmission electron microscope (TEM) and energy disperse spectroscopy (EDS) were used to characterize the microstructure of mesoporous Co3O4 and CoFe2O4/Co3O4 nanocomposites. The percent of pore-volume of mesoporous Co3O4 nanowires was calculated to be about 41.99% and CoFe2O4 nanoparticles were revealed to exist in the mesopores of Co3O4, The magnetic behavior of both samples were investigated with superconducting quantum interference device (SQUID). Magnetization increased with the doping CoFe2O4 and decreasing temperature, while coercivity hardly changed. The exchange bias effect was obviously observed at 100 K and enhanced with the doping CoFe2O4. CoFe2O4 nanoparticles reinforced the interfaces magnetic interaction between antiferromagnetic Co3O4 and ferrimagnetic CoFe2O4. (c) 2015 Elsevier B.V. All rights reserved.