A complex ternary BiPO4/TiO2/gC(3)N(4) heterostructure has been obtained from a simple impregnation method having good photoactivities for the degradation of phenol under solar-like irradiation. From the wide structural, surface and electronic characterization, we have stated that the formation of the ternary heterojunction notably affect photoactivity of pristine TiO2. Thus, the best result for the binary system was obtained for 70 wt%TiO2-30 wt% BiPO4 system. The incorporation of gC(3)N(4) leads to a further improvement on the photocatalytic activity when it is specifically done over TiO2. By means of photoluminescence spectroscopy and reactive oxygen species formation test, we propose that the effective charge carrier separation is taking place through a cascade-driven electronic mechanism. Therefore, by choosing the adequate band-engineering tailoring an important improved photoactivity can be achieved. (C) 2015 Elsevier B.V. All rights reserved.