자전연소합성법을 이용한 비정질 나노 붕소 분말 특성에 미치는 첨가제의 영향

주신형; Hayk H. Nersisyan; 이태혁; 조영희; 김홍물; 이혁희; 이종현; Sin Hyong Joo; Hayk H. Nersisyan; Tae Hyuk Lee; Young Hee Cho; Hong Moule Kim; Huk Hee Lee; Jong Hyeon Lee

Korean Journal of Materials Research, Vol.25, No.12, 659-665, December, 2015

DOI10.3740/MRSK.2015.25.12.659 Export Citation

자전연소합성법을 이용한 비정질 나노 붕소 분말 특성에 미치는 첨가제의 영향

Effect of Additives on the Characteristics of Amorphous Nano Boron Powder Fabricated by Self-Propagating High Temperature Synthesis

주신형^{1, 2}, Hayk H. Nersisyan^{1, 2}, 이태혁^{1, 2}, 조영희³, 김홍물³, 이혁희⁴, 이종현^{1, 2, †}

¹충남대학교 신소재공학과
²충남대학교 급속응고신소재연구소
³하나 AMT(주)
⁴한국화학연구원

Sin Hyong Joo^{1, 2}, Hayk H. Nersisyan^{1, 2}, Tae Hyuk Lee^{1, 2}, Young Hee Cho³, Hong Moule Kim³, Huk Hee Lee⁴, and Jong Hyeon Lee^{1, 2, †}

¹Graduate School of Department of Materials Science & Engineering, Chungnam National University, Daejeon 34134, Korea
²RASOM, Chungnam National University, Daejeon 28126, Korea
³Hana AMT, Cheongju 28126, Korea
⁴Research Center Institute of Chemical Technology, Daejeon 34114, Korea

E-mail:

The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nanopowders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the B2O3 + α Mg system(α = 1.0-8.0) in an argon atmospheres. In this study, the exothermic nature of the B2O3-Mg reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the B2O3 and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, Na2B4O7 and H3BO3 additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the B2O3 + α Mg system with 0.5 mole Na2B4O7 was identified to be amorphous boron nano-powders(< 100 nm).

Keywords:amorphous boron;SHS;microstructure;nano powder

[References]

Hui X, Kumar K, Sung CJ, Edwards T, Gardner D, Fuel, 98, 176 (2012)
Wilson GR, Edwards T, Corporan E, Freerks RL, Energy Fuels, 27(2), 962 (2013)
Sibi MG, Singh B, Kumar R, Pendem C, Sinha AK, Green Chem., 14, 976 (2012)
Wang L, Zou JJ, Zhang XW, Wang L, Fuel, 91(1), 164 (2012)
Van Devener B, Perez JPL, Jankovich J, Anderson SL, Energy Fuels, 23, 6111 (2009)
Pang WQ, Fan XZ, Zhang W, Xu HX, Li JZ, Li YH, Shi XB, Li Y, PROPELLANT-EXPLOS-PYROTECH, 36(4), 360 (2011)
Mohan S, Trunov MA, Dreizin EL, J. Propul. Power, 24, 199 (2008)
Yetter RA, Risha GA, Son SF, Proc. Combust. Inst., 32, 1819 (2009)
Gany A, Defense Sci. J., 56, 321 (2006)
Ulas A, Kuo KK, Gotzmer C, Combust. Flame, 127(1-2), 1935 (2001)
Karmakar S, Wang N, Acharya S, Dooley KM, Combust. Flame, 160(12), 3004 (2013)
Si PZ, Zhang M, You CY, Geng DY, Du JH, Zhao XG, Ma XL, Zhang ZD, J. Mater. Sci., 38(4), 689 (2003)
Bellott BJ, Noh W, Nuzzo RG, Girolami GS, Chem. Commun., 22, 3214 (2009)
Marzik JV, Suplinskas RJ, Wilke RHT, Canfield PC, Finnemore DK, Rindfleisch M, Margolies J, Hannahs ST, Physica C, 423, 83 (2005)
Pickering AL, Mitterbauer C, Browning ND, Kauzlarich SM, Power PP, Chem. Commun., 6, 580 (2007)
Van Devener B, Perez JPL, Jankovich J, Anderson SL, Energy Fuels, 23, 6111 (2009)
Vignolo M, Bovone G, Matera D, Nardelli D, Bernini C, Siri AS, Chem. Eng. J., 256, 32 (2014)
Shin CY, Yun KS, Park YC, Nersisyan HH, Won CW, J. Korean Ceram. Soc., 42, 22 (2005)
Liu XY, Zhao XD, Hou XWM, Su WH, J. Alloy. Compd., 223, L7 (1995)
Adasch V, Hess KW, Ludwig T, Vojteer N, Hillebrecht H, J. Solid State Chem., 179, 2916 (2006)
Lorenz H, Orgzall I, Scr. Mater., 52, 537 (2005)

[1] Hui X, Kumar K, Sung CJ, Edwards T, Gardner D, Fuel, 98, 176 (2012)

[2] Wilson GR, Edwards T, Corporan E, Freerks RL, Energy Fuels, 27(2), 962 (2013)

[3] Sibi MG, Singh B, Kumar R, Pendem C, Sinha AK, Green Chem., 14, 976 (2012)

[4] Wang L, Zou JJ, Zhang XW, Wang L, Fuel, 91(1), 164 (2012)

[5] Van Devener B, Perez JPL, Jankovich J, Anderson SL, Energy Fuels, 23, 6111 (2009)

[6] Pang WQ, Fan XZ, Zhang W, Xu HX, Li JZ, Li YH, Shi XB, Li Y, PROPELLANT-EXPLOS-PYROTECH, 36(4), 360 (2011)

[7] Mohan S, Trunov MA, Dreizin EL, J. Propul. Power, 24, 199 (2008)

[8] Yetter RA, Risha GA, Son SF, Proc. Combust. Inst., 32, 1819 (2009)

[9] Gany A, Defense Sci. J., 56, 321 (2006)

[10] Ulas A, Kuo KK, Gotzmer C, Combust. Flame, 127(1-2), 1935 (2001)

[11] Karmakar S, Wang N, Acharya S, Dooley KM, Combust. Flame, 160(12), 3004 (2013)

[12] Si PZ, Zhang M, You CY, Geng DY, Du JH, Zhao XG, Ma XL, Zhang ZD, J. Mater. Sci., 38(4), 689 (2003)

[13] Bellott BJ, Noh W, Nuzzo RG, Girolami GS, Chem. Commun., 22, 3214 (2009)

[14] Marzik JV, Suplinskas RJ, Wilke RHT, Canfield PC, Finnemore DK, Rindfleisch M, Margolies J, Hannahs ST, Physica C, 423, 83 (2005)

[15] Pickering AL, Mitterbauer C, Browning ND, Kauzlarich SM, Power PP, Chem. Commun., 6, 580 (2007)

[16] Van Devener B, Perez JPL, Jankovich J, Anderson SL, Energy Fuels, 23, 6111 (2009)

[17] Vignolo M, Bovone G, Matera D, Nardelli D, Bernini C, Siri AS, Chem. Eng. J., 256, 32 (2014)

[18] Shin CY, Yun KS, Park YC, Nersisyan HH, Won CW, J. Korean Ceram. Soc., 42, 22 (2005)

[19] Liu XY, Zhao XD, Hou XWM, Su WH, J. Alloy. Compd., 223, L7 (1995)

[20] Adasch V, Hess KW, Ludwig T, Vojteer N, Hillebrecht H, J. Solid State Chem., 179, 2916 (2006)

[21] Lorenz H, Orgzall I, Scr. Mater., 52, 537 (2005)