화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.34, 321-326, February, 2016
DOI10.1016/j.jiec.2015.12.007  Export Citation
Pervaporative recovery of tetrahydrofuran from water with plasticized and filled polyvinylchloride membranes
Paramita Das, and Samit Kumar Ray†
  • Department of Polymer Science and Technology, University of Calcutta, 92, A.P.C. Road, Kolkata 700009, India
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Plasticized polyvinyl chloride (PPVC) membranes were prepared by incorporating 20, 25 and 30 wt% of dioctyl phthalate (DOP) plasticizer in the matrix of PVC. Filled PPVC membranes were prepared by incorporating 1, 2 and 3 wt% bentonite clay in the PPVC membrane containing 25 wt% of DOP. The membranes were characterized by FTIR, DTA-TG, XRD, SEM and mechanical properties. These membranes were used for sorption and pervaporation of 1-18 wt% tetrahydrofuran (THF) in water. The preferential sorption of the organophilic membranes were analyzed in terms of thermodynamic interaction parameters. The permeability and the diffusion coefficient of the solvents were determined.
Keywords:Plasticized PVC;Bentonite clay;Interaction parameter;Pervaporation;THF recovery
  1. Boddeker KW, Bengtson G, in: Huang RYM (Ed.), Pervaporation Membrane Separation Processes, Elsevier, Amsterdam, 1991, p. 452.
  2. Baker RW, Membrane Technology and Applications, John Wiley and Sons Ltd., West Sussex, England, 2004.
  3. Ray SK, Sawant SB, Joshi JB, Pangarkar VG, Ind. Eng. Chem. Res., 36(12), 5265 (1997)
  4. Peng M, Vane LM, Liu SX, J. Hazard. Mater., 98(1-3), 69 (2003)
  5. Vane LM, Namboodiri VV, Bowen TC, J. Membr. Sci., 308(1-2), 230 (2008)
  6. Kiani A, Shahbazi M, Asempour H, J. Appl. Polym. Sci., 124(1), 99 (2012)
  7. Singha NR, Ray S, Ray SK, Konar BB, J. Appl. Polym. Sci., 121(3), 1330 (2011)
  8. Singha NR, Das P, Ray SK, J. Ind. Eng. Chem., 19(6), 2034 (2013)
  9. Ray S, Ray SK, J. Membr. Sci., 270(1-2), 132 (2006)
  10. George SG, Thomas S, Prog. Polym. Sci, 26, 985 (2001)
  11. Ray S, Singha NR, Ray SK, Chem. Eng. J., 149(1-3), 153 (2009)
  12. Cox G, Baker RW, Ind. Waste Water, 6, 35 (1998)
  13. Muller H, in: Elvers B, Hawkins S, Russey W (Eds.), Ullmann’s Encyclopedia of Industrial Chemistry, A26, VCH Verlagsgesellschaft mbH, D-69451, Weinheim (Federal Republic of Germany), 1995, pp. 221-226.
  14. Han YJ, Su WC, Lai JY, Liu YL, J. Membr. Sci., 475, 496 (2015)
  15. Kuila SB, Ray SK, Sep. Purif. Technol., 89, 39 (2012)
  16. Ray S, Ray SK, Chem. Eng. Process., 47(9-10), 1620 (2008)
  17. Chapman P, Loh XX, Livingston AG, Li K, Oliveira TAC, J. Membr. Sci., 309(1-2), 102 (2008)
  18. Ray S, Ray SK, Sep. Purif. Technol., 50(2), 156 (2006)
  19. Devi DA, Smitha B, Sridhar S, Aminabhavi TM, J. Membr. Sci., 280(1-2), 45 (2006)
  20. Chapman PD, Tan XY, Livingston AG, Li K, Oliveira T, J. Membr. Sci., 268(1), 13 (2006)
  21. Ray S, Ray SK, J. Appl. Polym. Sci., 103, 728 (2006)
  22. Chapman PD, Oliveira T, Livingston AG, Li K, J. Membr. Sci., 318(1-2), 5 (2008)
  23. Claes S, Vandezande P, Mullens S, Adriaensens P, Peeters R, Maurer FHJ, Van Bael MK, J. Membr. Sci., 389, 459 (2012)
  24. Ortiz LJG, Arellano M, Jasso CF, Mendizabal E, Pena MJS, Polym. Degrad. Stabil., 90, 154 (2005)
  25. Yu Z, Liu X, Zhao F, Liang X, Tian Y, J. Appl. Polym. Sci., http://dx.doi.org/10.1002/APP.41267. (2015)
  26. Yildirim AE, Hilmioglu ND, Tulbentci S, Chem. Eng. Technol., 24(3), 275 (2001)
  27. An QF, Qian JW, Sun HB, Wang LN, Zhang L, Chen HL, J. Membr. Sci., 222(1-2), 113 (2003)
  28. Zhang XL, Qian LP, Wang HT, Zhong W, Du QG, Sep. Purif. Technol., 63(2), 434 (2008)
  29. Aouinti L, Roizard D, Hu GH, Thomas F, Belbachir M, Desalination, 241(1-3), 174 (2009)
  30. Chiellini F, Ferri M, Morellia A, Dipaola L, Latini G, Prog. Polym. Sci, 38, 1067 (2013)
  31. van Oosterhout JT, Gilbert M, Polymer, 44(26), 8081 (2003)
  32. Langmaier J, Stejskalova K, Samec Z, J. Electroanal. Chem., 521(1-2), 81 (2002)
  33. Yu Q, Selvadurai APS, Polym. Degrad. Stabil., 89, 109 (2005)
  34. Brydson JA, Plastics Materials, 7th ed., Butterworth Heinemann, Oxford, 1999.
  35. Xiao S, Feng X, Huang RYM, J. Membr. Sci., 302(1-2), 36 (2007)
  36. Mulder MHV, Smolders CA, J. Membr. Sci., 17, 289 (1984)
  37. Polotskaya GA, Meleshko TK, Sushchenko IG, Yakimansky AV, Pulyalina AY, Toikka AM, Pientka Z, J. Appl. Polym. Sci., 117(4), 2175 (2010)
  38. Hirata M, Ohe S, Nagahama K, Computer aided Data Book of Vapor-Liquid Equilibria, Kodansha Limited, Elsevier Scientific Co., Tokyo, 1985.
  39. Favre E, Nguyen QT, Clement R, Neel J, J. Membr. Sci., 117(1-2), 227 (1996)
  40. Baker RW, Wijmans JG, Huang Y, J. Membr. Sci., 348(1-2), 346 (2010)
  41. Lue SJ, Ou JS, Kuo CH, Chen HY, Yang TH, J. Membr. Sci., 347(1-2), 108 (2010)
  42. Samanta HS, Ray SK, Sep. Purif. Technol., 143, 52 (2015)
  43. Ramesh A, Leen KH, Kumutha K, Arof AK, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 66, 1237 (2007)
  44. da Silva MA, Vieira MGA, Macumoto ACG, Beppu MM, Polym. Test, 30, 478 (2011)
  45. Stephan AM, Kumar TP, Renganathan NG, Pitchumani S, Thirunakaran R, Muniyandi N, J. Power Sources, 89(1), 80 (2000)
  46. de Souza ML, deSouza ER, Cario P, Temperino MLA, Vibrational Characterization of Plasticized PVC by FTIR and FTRAMAN in Modern Topics in Raman Spectroscopy, Sao Paulo, Brasil, 2014.
  47. Soudais Y, Moga L, Blazek J, Lemort F, J. Anal. Appl. Pyrolysis, 78, 46 (2007)
  48. Djidjelli H, Kaci M, Boukerrou A, Benachour D, Martinez-Vega JJ, J. Appl. Polym. Sci., 89(13), 3447 (2003)
  49. Sullad AG, Manjeshwar LS, Aminabhavi TM, J. Appl. Polym. Sci., 117(3), 1361 (2010)
  50. Rogers CE, in: Comyn J (Ed.), Polymer Permeability, Elsevier Applied Sciences, New York, 1985.
  51. Samanta HS, Ray SK, Das P, Singha NR, J. Chem. Technol. Biotechnol., 87(5), 608 (2012)
  52. Nagase Y, Ando T, Yun CM, React. Funct. Polym., 67(11), 1252 (2007)
  53. Tuan VA, Li S, Falconer JL, Noble RD, Chem. Mater., 14(2), 489 (2002)
  54. Piera E, Coronas J, Santamaria MMJ, Chem. Commun., 309, 1309 (1999)
  55. Samanta HS, Ray SK, Sep. Purif. Technol., 146, 176 (2015)