화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.34, 244-249, February, 2016
DOI10.1016/j.jiec.2015.11.01  Export Citation
Adsorptive properties of molasses modified boron enrichment waste based nanoclay for removal of basic dyes
Vinod Kumar Gupta1, 2, †, Shilpi Agarwal3, Asim Olgun4, Halil Ibrahim Demir5, Mehmet Lutfi Yola6, and Necip Atar7
  • 1Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, Uttarakhand, India
  • 2Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa, India
  • 3Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa, Korea
  • 4Department of Chemistry, Dumlupinar University, Kutahya, Turkey
  • 5Department of Elementary Education, Dumlupinar University, Kutahya, Turkey
  • 6Department of Metallurgical and Materials Engineering, Sinop University, Sinop, Turkey
  • 7Department of Chemical Engineering, Pamukkale University, Denizli, Turkey
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In this study, the removal of cationic dyes, Basic Red 46 (BR46) and Basic Blue 41 (BB41), from aqueous solution using boron enrichment waste (BW) and molasses modified boron enrichment waste (MBW) based nanoclays was presented in a batch system and fixed-bed column system. The effects of pH, contact time, initial solution concentration, adsorbent dosage, temperature of batch operation on the uptake of both dyes were investigated. The adsorption data were further performed on the basis of kinetic and isotherm models. According to the results, the dye removal capacity of MBW was higher than that of BW. The studies demonstrated that the adsorption patterns occurred according to Langmuir isotherm model and pseudo-second-order kinetic model. The adsorption of two dyes is spontaneous and exothermic in nature. Breakthrough curves obtained from fixed-bed column tests showed that column adsorption capacities provided strong evidence of the potential of the nanoclay for the technological applications of the basic dyes removal from aqueous solutions.
Keywords:Adsorption;Molasses;Boron Industry Waste;Basic dyes;Isotherm
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