화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.34, 224-232, February, 2016
DOI10.1016/j.jiec.2015.11.013  Export Citation
Experimental design for optimization of olive mill wastewater final purification with Dowex Marathon C and Amberlite IRA-67 ion exchange resins
Marıa Dolores Vıctor-Ortega†, Javier Miguel Ochando-Pulido, Diego Airado-Rodrıguez1, and Antonio Martınez-Ferez
  • Chemical Engineering Department, University of Granada, 18071 Granada, Spain
  • 1Nofima AS—The Norwegian Institute of Food, Fisheries and Aquaculture Research, Osloveien 1, 1430 A˚s, Norway
E-mail:
The final purification of two-phase olive mill wastewater (OMW-2) by ion exchange (IE) was addressed. This pollutant effluent was previously subjected to Pseudo-Fenton secondary treatment. Consequently, OMW-2 presented high concentrations of chloride, sodium, phenols and iron, which hinder its discharge. Experimental design was used to optimize the IE process. Around 88% removal efficiencies of these pollutants were achieved when initial pH, temperature and flow rate were 5.1, 26.8 ℃ and 12.1 L h-1, respectively. Finally, 28 L treated water could be accomplished in continuous mode under optimal conditions, complying with standards for reuse in the olive oil production process.
Keywords:Central composite design;Ion exchange;Olive mill wastewater;Pollutants;Response surface
  1. Dhouib A, Aloui F, Hamad N, Sayadi S, Process Biochem., 41, 159 (2006)
  2. Kestioglu K, Yonar T, Azbar N, Process Biochem., 40, 2409 (2005)
  3. FAIR CT96-1420, Annex 2. .
  4. Demirbas A, Pehlivan E, Gode F, Altun T, Arslan G, J. Colloid Interface Sci., 282(1), 20 (2005)
  5. Balcioglu G, Gonder ZB, Chem. Eng. J., 255, 630 (2014)
  6. Chen H, Dai GL, Zhao J, Zhong AG, Wu JY, Yan H, J. Hazard. Mater., 177(1-3), 228 (2010)
  7. Das N, Hydrometallurgy, 103, 180 (2010)
  8. Fu F, Wang Q, J. Environ. Manage., 92, 407 (2011)
  9. Li L, Liu F, Jing X, Ling P, Li A, Water Res., 45, 1177 (2011)
  10. Gupta SS, Bhattacharyya KG, J. Colloid Interface Sci., 162, 39 (2011)
  11. Annesini M, Gironi F, Water Res., 25, 1157 (1991)
  12. Niaounakis M, Halvadakis CP, Waste Management Series 5, second ed., Elsevier, Amsterdam, 2006p. 23.
  13. Cegarra J, Paredes C, Roig A, Bernal MP, Garcıa D, Int. Biodeterior. Biodegrad., 38(3-4), 193 (1996)
  14. Papadimitriou EK, Chatjipavlidis I, Balis C, Environ. Technol., 18(1), 101 (1997)
  15. Al-Malah K, Azzam MOJ, Abu-Lail NI, Sep. Purif. Technol., 20(2-3), 225 (2000)
  16. Aktas ES, Imre S, Esroy L, Water Res., 35, 2336 (2001)
  17. Hodaifa G, Ochando-Pulido JM, Rodriguez-Vives S, Martinez-Ferez A, Chem. Eng. J., 220, 117 (2013)
  18. Nieto LM, Hodaifa G, Vives SR, Casares JAG, Ochando J, Clean-Soil Air Water, 39(10), 949 (2011)
  19. Sarika R, Kalogerakis N, Mantzavinos D, Environ. Int., 31, 297 (2005)
  20. Papastefanakis N, Mantzavinos D, Katsaounis A, J. Appl. Electrochem., 40(4), 729 (2010)
  21. Un UT, Altay U, Koparal AS, Ogutveren UB, Chem. Eng. J., 139(3), 445 (2008)
  22. de Heredia JB, Garcia J, Ind. Eng. Chem. Res., 44(23), 8750 (2005)
  23. de Caprariis B, Di Rita M, Stoller M, Verdone N, Chianese A, Chem. Eng. Sci., 76, 73 (2012)
  24. Hoyos SEG, Nieto LM, Rubio FC, Cormenzana AR, Process Biochem., 37(10), 1169 (2002)
  25. Paraskeva P, Diamadopoulos E, J. Chem. Technol. Biotechnol., 81, 475 (2006)
  26. Al-Qodah Z, Al-Shannag M, Bani-Melhem K, Assirey E, Alananbeh K, Bouqellah N, Desalin. Water Treat., http://dx.doi.org/10.1080/19443994.2014.954148 (In press). (2014)
  27. Lafi WK, Shannak B, Al-Shannag M, Al-Anber Z, Al-Hasan M, Sep. Purif. Technol., 70(2), 141 (2009)
  28. Rizzo L, Lofrano G, Grassi M, Belgiorno V, Sep. Purif. Technol., 63(3), 648 (2008)
  29. Al-Qodah Z, Al-Bsoul A, Assirey E, Al-Shannag M, Environ. Eng. Manage. J., 8, 2109 (2014)
  30. Lafi WK, Al-Anber M, Al-Anber ZA, Al-Shannag M, Khalil A, Desalin. Water Treat., 24, 251 (2010)
  31. Nieto LM, Hodaifa G, Rodriguez S, Gimenez JA, Ochando J, Chem. Eng. J., 173(2), 503 (2011)
  32. Hodaifa G, Ochando-Pulido JM, Alami SBD, Rodriguez-Vives S, Martinez-Ferez A, Ind. Crop. Prod., 49, 526 (2013)
  33. European Commission, Council Directive 80/778/EEC of 15 July 1980 on the Quality of Water Intended for Human Consumption, European Commission, 1980 1980.
  34. European Commission, Council Directive 98/83/EC of 3 November 1998 on the Quality of Water Intended for Human Consumption, European Commission, 1998.
  35. Comstock SEH, Boyer TH, Chem. Eng. J., 241, 366 (2014)
  36. ElNaggar IM, ElDessouky ME, Aly HF, React. Funct. Polym., 28(2), 209 (1996)
  37. Pivovarov S, J. Colloid Interface Sci., 319(1), 374 (2008)
  38. Vı´ctor-Ortega MD, Ochando-Pulido JM, Martınez-Ferez A, Ecol. Eng., 77, 18 (2015)
  39. Abburi K, J. Hazard. Mater., 105(1-3), 143 (2003)
  40. Caetano M, Valderrama C, Farran A, Cortina JL, J. Colloid Interface Sci., 338(2), 402 (2009)
  41. Carmona M, De Lucas A, Valverde JL, Velasco B, Rodriguez JF, Chem. Eng. J., 117(2), 155 (2006)
  42. Keller M, Water Cond. Purif., 46(6), 20 (2004)
  43. Ku Y, Lee KC, Wang W, Sep. Sci. Technol., 39(4), 911 (2004)
  44. Ostroski IC, Barros MASD, Silva EA, Dantas JH, Arroyo PA, Lima OCM, J. Hazard. Mater., 161(2-3), 1404 (2009)
  45. Tahir SS, Rauf N, J. Environ. Manage., 73, 285 (2004)
  46. Vaaramaa K, Lehto J, Desalination, 155(2), 157 (2003)
  47. Ochando-Pulido JM, Hodaifa G, Rodriguez-Vives S, Martinez-Ferez A, Water Res., 46(15), 4621 (2012)
  48. Greenberg AE, Clesceri LS, Eaton AD, Standard Methods for the Examination of Water and Wastewater, sixteenth ed., APHA/AWWA/WEF, Washington, DC, 1992, Cabs.
  49. Elibol M, Process Biochem., 38, 667 (2002)
  50. Ravikumar K, Deebika B, Balu K, J. Hazard. Mater., 122(1-2), 75 (2005)
  51. Box GEP, Wilson KBJ, J. R. Stat. Soc. Ser., B(13), 1 (1951)
  52. Annadurai G, Juang RS, Lee DJ, Adv. Environ. Res., 6, 191 (2002)
  53. Victor-Ortega MD, Ochando-Pulido JM, Hodaifa G, Martinez-Ferez A, Desalination, 343, 198 (2014)
  54. Victor-Ortega MD, Ochando-Pulido JM, Hodaifa G, Martinez-Ferez A, Chem. Eng. Process., 85, 241 (2014)
  55. Kumar PS, Gayathri R, J. Eng. Sci. Technol., 4(4), 381 (2009)
  56. Chen JP, Chua ML, Zhang B, Waste Manage., 22, 711 (2002)
  57. Roostaei N, Tezel FH, J. Environ. Manage., 70, 157 (2004)
  58. Erdem E, Colgecen G, Donat R, J. Colloid Interface Sci., 282(2), 314 (2005)
  59. Zhu LL, Deng YF, Zhang JP, Chen J, J. Colloid Interface Sci., 364(2), 462 (2011)
  60. Habuda-Stanic M, Kalajdzic B, Kules M, Velic N, Desalination, 229(1-3), 1 (2008)
  61. Krishnan KA, Anirudhan TS, Water SA, 29(2), 147 (2003)
  62. Rengaraj S, Moon SH, Water Res., 36(7), 1783 (2002)
  63. Yu LJ, Shukla SS, Dorris KL, Shukla A, Margrave JL, J. Hazard. Mater., 100, 53 (2013)
  64. Garcia-Castello E, Cassano A, Criscuoli A, Conidi C, Drioli E, Water Res., 44, 3883 (2010)
  65. Cassano A, Conidi C, Drioli E, Water Res., 45, 3197 (2011)