화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.23, No.11, 977-985, November, 2015
DOI10.1007/s13233-015-3132-z  Export Citation
The synthesis of N-methylbis [2-(dodecylthio)ethyl]amine (SNS) and investigation of its efficiency as new mononuclear catalyst complex in copper-based ATRP
Hassan Hajifatheali, Ebrahim Ahmadi†, Andrzej Wojtczak1, and Zvonko Jaglicic2
  • Department of Chemistry, University of Zanjan, P.O. Box 45195-313, Zanjan, Islamic Republic of Iran
  • 1Department of Chemistry, Nicolaus Copernicus University, 87-100, Torun, Poland, Korea
  • 2Institute of Mathematics, Physics and Mechanics & Faculty of Civil and Geodetic Engineering, University of Ljubljana, Jadranska 19, SI-1000, Ljubljana, Slovenia, Slovakia (Slovak Republic)
E-mail:
This study is a report on atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) using a ligand, N-methylbis[2-(dodecylthio)ethyl]amine (SNS), which is tridentate ligand with mixed donor atoms. This ligand was synthesized in a simple way and at a low cost and was used to prepare a Cu catalyst complex (Cu/SNS) during the process of polymerization. The effects of various factors such as different molar ratios (100, 300, and 700 [monomer]:[initiator]) and cuprous halides (Br and Cl) on the polymerization of this ligand were investigated. The resulting catalyst complex mediated a living polymerization of MMA, yielding polymers with controlled molecular weights and narrow molecular weight distributions (1.09 < PDI < 1.4). The Highest PDI values were observed in the polymerization of the 700 molar ratio. The ligand, catalyst crystals formed at the end of polymerization, and synthesized polymers were characterized via UV-VIS, FTIR, CV, NMR, and GPC spectroscopy and single crystal X-ray crystallography as appropriate. The X-ray results for catalyst crystals showed that the catalyst was the deactivator (CuII Br2/SNS) of the ATRP equation and existed as a mononuclear catalyst complex.
Keywords:atom transfer radical polymerization;methyl methacrylate;SNS ligand;catalyst complex
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